The Kennepohl Research Group

publications

Publications

We are a diverse group with many interests which has led to many publications.  Below you will find published articles involving many of the members of our Kennepohl Research Group.

Publications

2020

  1. π Covalency in the Halogen Bond, Kellett, C., W.; Kennepohl, P.; and Berlinguette, C., P. Nat Commun 11, 3310 (2020). https://doi.org/10.1038/s41467-020-17122-7  (PDF)

2019

  1. Regiocontrolled and Stereoselective Syntheses of Tetrahydrophthalazine Derivatives using Radical Cyclizations. Zhang, W.; Mo, J., Y.; He, W.; Kennepohl, P.; and Sammis, G., M. Chemistry – A European Journal, 25: 976-980. 12 2019.  (PDF)
  2. Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus–Sulfur Material Having the Composition P 2 S, a Vulcanized Red Phosphorus That Is Yellow. Transue, W., J.; Nava, M.; Terban, M., W.; Yang, J.; Greenberg, M., W.; Wu, G.; Foreman, E., S.; Mustoe, C., L.; Kennepohl, P.; Owen, J., S.; Billinge, S., J., L.; Kulik, H., J.; and Cummins, C., C. Journal of the American Chemical Society, 141(1): 431-440. 1 2019. (PDF)
  3. Mechanistic insight into organic and industrial transformations: general discussion. Aoki Y, Bauer M, Braun T, Cadge JA, Clarke GE, Durand DJ, Eisenstein O, Gallarati S, Greaves M, Harvey J, Haynes A, Hintermair U, Hulme AN, Ishii Y, Jakoobi M, Jensen VR, Kennepohl P, Kuwata S, Lei A, Lloyd-Jones G, Love J, Lynam J, Macgregor S, Morris RH, Nelson D, Odom A, Perutz R, Reiher M, Renny J, Roithova J, Schafer L, Scott S, Seavill PW, Slattery J, Takao T, Walton J, Wilden JD, Wong CY, Young T. Faraday Discuss. 2019 Dec 2;220(0):282-316. doi: 10.1039/C9FD90072A. PMID: 31754665
  4. The Importance of Ligand-Induced Backdonation in the Stabilization of Square Planar d 10 Nickel π-Complexes. Desnoyer, A., N.; He, W.; Behyan, S.; Chiu, W.; Love, J., A.; and Kennepohl, P. Chemistry - A European Journal, 25(20): 5259-5268. 2019. (PDF)
  5. Green synthesis of copper oxide nanoparticles using sinapic acid: an underpinning step towards antiangiogenic therapy for breast cancer. Raj Preeth, D.; Shairam, M.; Suganya, N.; Roshandel, H.; R.; Kartik, R.; Kennepohl, K..; Suvro, C.; and Rajalakshmi, S. JBIC Journal of Biological Inorganic Chemistry, 24(5): 633-645. 8 2019.  (PDF)
  6. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes. He, W.; and  Kennepohl, P. Faraday Discussions, 220: 133-143. 2019. (PDF)
  7. Physical methods for mechanistic understanding: general discussion. Aoki, Y.; Bauer, M.; Braun, T.; Cadge, J.; Davies, D.; Durand, D., J.; Eisenstein, O.; Ess, D.; Fairlamb, I.; Fey, N.; Gallarati, S.; George, M.; Greaves, M.; Halse, M.; Hamilton, A.; Harvey, J.; Haynes, A.; Hintermair, U.; Hulme, A., N.; Ishii, Y.; Jakoobi, M.; Jensen, V., R.; Kennepohl, P.; Kuwata, S.; Lei, A.; Lloyd-Jones, G.; Love, J.; Lovelock, K.; Lynam, J.; Macgregor, S.; Marder, T., B.; Meijer, E., J.; Morgan, P.; Morris, R., H.; Mwansa, J.; Nelson, D.; Odom, A.; Perutz, R.; Reiher, M.; Renny, J.; Roithová, J.; Schafer, L.; Schilter, D.; Scott, S.; Slattery, J.; Walton, J.; Wilden, J., D.; Wong, C.; Yaman, T.; and Young, T. Faraday Discussions, 220: 144-178. 2019. (PDF)

 

 

  1. Reacted copper(II) concentrations in amine amended micronized copper treated red pine and lodgepole pine. Xue, W.; Kennepohl, P.; and Ruddick, J., N., R. Eur. J. Wood Prod., 76(1): 337-343. 1 2018. (PDF)
  2. Disproportionation Reactions of an Organometallic Ni(I) Amidate Complex: Scope and Mechanistic Investigations. Beattie, D., D.; Lascoumettes, G.; Kennepohl, P.; Love, J., A.; and Schafer, L., L. Organometallics, 37(9): 1392-1399. 5 2018. (PDF)
  3. Identifying the missing link in catalyst transfer polymerization. He, W.; Patrick, B., O.; and Kennepohl, P. Nature Communications, 9(1): 3866. 12 2018. (PDF)
  1. Spectroscopic detection of halogen bonding resolves dye regeneration in the dye-sensitized solar cell. Parlane, F., G., L.; Mustoe, C., L.; Kellett, C., W.; Simon, S., J.; Swords, W., B.; Meyer, G., J.; Kennepohl, P.; and Berlinguette, C., P. Nature Commun., 8(1): 1761. 12 2017. (PDF)
  2. Beyond the halogen bond: general discussion. Aakeröy, C., B.; Alavi, S.; Beer, P., D.; Beyeh, N., K.; Brammer, L.; Bryce, D., L.; Clark, T.; Cottrell, S., J.; Del Bene, J., E.; Edwards, A., J.; Esterhuysen, C.; Friščić, T.; Guru Row, T., N.; Kennepohl, P.; Lloyd, G., O.; Roy Choudhury, A.; Scheiner, S.; Southern, S., A.; Taylor, M., S.; Tsuzuki, S.; and Vargas-Baca, I. Faraday Discuss., 203: 227-244. 2017.
  3. The halogen bond in solution: general discussion. Aakeröy, C., B.; Beer, P., D.; Beyeh, N., K.; Brammer, L.; Branca, M.; Bryce, D., L.; Del Bene, J., E.; Edwards, A., J.; Erdelyi, M.; Esterhuysen, C.; Fourmigué, M.; Kennepohl, P.; Lee, L., M.; Mosquera, M., E., G.; Murray, J., S.; Mustoe, C., L.; Pennington, W., T.; Politzer, P.; Riley, K., E.; Rosokha, S., V.; Scheiner, S.; Taylor, M., S.; Tsuzuki, S.; Vargas-Baca, I.; and Xu, Y. Faraday Discuss., 203: 347-370. 2017.
  4. Computational approaches and sigma-hole interactions: general discussion. Aakeröy, C., B.; Alavi, S.; Brammer, L.; Bryce, D., L.; Clark, T.; Del Bene, J., E.; Edwards, A., J.; Esterhuysen, C.; Guru Row, T., N.; Kennepohl, P.; Legon, A., C.; Lloyd, G., O.; Murray, J., S.; Pennington, W., T.; Politzer, P.; Riley, K., E.; Rosokha, S., V.; Scheiner, S.; Tsuzuki, S.; and Vargas-Baca, I. Faraday Discuss., 203: 131-163. 2017.
  5. Probing covalency in halogen bonds through donor K-edge X-ray absorption spectroscopy: polyhalides as coordination complexes. Mustoe, C., L.; Gunabalasingam, M.; Yu, D.; Patrick, B., O.; and Kennepohl, P. Faraday Discuss., 203: 79-91. 2017.
  6. Mechanisms of varnish formation and implications for the use of varnish-removal technology. Hobbs, M.; Dufresne, P.; Behyan, S.; and Kennepohl, P. In 72nd Annual Meeting and Exhibition of the Society of Tribologists and Lubrication Engineers, STLE 2017, 2017.
  7. Solid-state chemistry and applications: general discussion. Aakeröy, C., B.; Alavi, S.; Beyeh, N., K.; Brammer, L.; Branca, M.; Bryce, D., L.; Christopherson, J.; Clark, T.; Cottrell, S., J.; Del Bene, J., E.; Dichiarante, V.; Edwards, A., J.; Erdelyi, M.; Esterhuysen, C.; Fourmigué, M.; Friščić, T.; Kennepohl, P.; Legon, A., C.; Lloyd, G., O.; Murray, J., S.; Mustoe, C., L.; Pennington, W., T.; Rosokha, S., V.; Roy Choudhury, A.; Scheiner, S.; Szell, P., M., J.; Taylor, M., S.; and Tsuzuki, S. Faraday Discuss., 203(459): 459-483. 2017.
  1. Reexamining Oxidation States during the Synthesis of 2-Rhodaoxetanes from Olefins.  Desnoyer, A., N.; Behyan, S.; Patrick, B., O.; Dauth, A.; Love, J., A.; and Kennepohl, P. Inorg. Chem., 55(1): 13-15. 1 2016. (PDF)
  2. Even the normal is abnormal: N-heterocyclic carbene C 2 binding to a phosphaalkene without breaking the P-C π-bond. Majhi, P., K.; Chow, K., C., F.; Hsieh, T., H., H.; Bowes, E., G.; Schnakenburg, G.; Kennepohl, P.; Streubel, R.; and Gates, D., P. Chem. Commun., 52(5): 998-1001. 2016.(PDF)
  3. Solubilisation and chemical fixation of copper(II) in micronized copper treated wood. Xue, W.; Ruddick, J., N., R.; and Kennepohl, P. Dalton Trans., 45(9): 3679-3686. 2016. (PDF)
  4. Interactions between major chlorogenic acid isomers and chemical changes in coffee brew that affect antioxidant activities. Liang, N.; Xue, W.; Kennepohl, P.; and Kitts, D., D. Food Chemistry, 213: 251-259. 12 2016. (PDF)
  1. Reacted copper(II) concentrations in earlywood and latewood of micronized copper-treated Canadian softwood species. Xue, W.; Kennepohl, P.; and Ruddick, J., N. Holzforschung, 69(4): 509-512. 2015. (PDF)
  2. Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant. Chong, E.; Xue, W.; Storr, T.; Kennepohl, P.; and Schafer, L., L. Organometallics, 34(20): 4941-4945. 10 2015. (PDF)
  3. Electrophilic Activation of Oxidized Sulfur Ligands and Implications for the Biological Activity of Ruthenium(II) Arene Anticancer Complexes. Sriskandakumar, T.; Behyan, S.; Habtemariam, A.; Sadler, P., J.; and Kennepohl, P. Inorg. Chem., 54(23): 11574-11580. 12 2015. (PDF)
  4. Evidence for Halogen Bond Covalency in Acyclic and Interlocked Halogen-Bonding Receptor Anion Recognition. Robinson, S., W.; Mustoe, C., L.; White, N., G.; Brown, A.; Thompson, A., L.; Kennepohl, P.; and Beer, P., D. J. Am. Chem. Soc., 137(1): 499-507. 1 2015. (PDF)
  5. Characterization of Copper in Leachates from ACQ- and MCQ-treated wood and its effects on Basidiopore Germination. Stirling, R.; Ruddick, J., N., R., R.; Xue, W.; Morris, P., I.; and Kennepohl, P. Wood Fiber Sci., 47(3): 209-216. 2015.
  1. 3-Rhoda-1,2-diazacyclopentanes: A Series of Novel Metallacycle Complexes Derived From C-N Functionalization of Ethylene. Drover, M., W.; Beh, D., W.; Kennepohl, P.; and Love, J., A. Chem. Eur. J., 20(41): 13345-55. 10 2014. (PDF)
  1. Preface. Chen, P.; Gamelin, D., R.; and Kennepohl, P. Coord. Chem. Rev., 257(1): 1-2. 1 2013.  (PDF)
  2. Quantification of mobilized copper(II) levels in micronized copper-treated wood by electron paramagnetic resonance (EPR) spectroscopy. Xue, W.; Kennepohl, P.; and Ruddick, J., N. Holzforschung, 67(7): 815-823. 1 2013. (PDF)
  3. Dioxygen adducts of rhodium N-heterocyclic carbene complexes. Keske, E., C.; Zenkina, O., V.; Asadi, A.; Sun, H.; Praetorius, J., M.; Allen, D., P.; Covelli, D.; Patrick, B., O.; Wang, R.; Kennepohl, P.; James, B., R.; and Crudden, C., M. Dalton Trans., 42(20): 7414. 5 2013. (PDF)
  1. Fluorine transfer to alkyl radicals. Rueda-Becerril, M.; Sazepin, C., C.; Leung, J., C., T.; Okbinoglu, T.; Kennepohl, P.; Paquin, J.; and Sammis, G., M. J. Am. Chem. Soc., 134(9): 4026-9. 3 2012. (PDF)
  2. Investigation of copper solubilization and reaction in micronized copper treated wood by electron paramagnetic resonance (EPR) spectroscopy. Xue, W.; Kennepohl, P.; and Ruddick, J., N. Holzforschung, 66(7): 889–895. 1 2012. (PDF)
  3. Synthesis and Characterization of Cationic Rhodium Peroxo Complexes. Cipot-Wechsler, J.; Covelli, D.; Praetorius, J., M.; Hearns, N.; Zenkina, O., V.; Keske, E., C.; Wang, R.; Kennepohl, P.; and Crudden, C., M. Organometallics, 31(21): 7306-7315. 11 2012. (PDF)
  1. Electronic structure of S-nitrosothiols from sulfur K-edge X-ray absorption spectroscopy. Martin-Diaconescu, V.; Perepichka, I.; Bohle, D., S.; and Kennepohl, P. Can. J. Chem., 89(2): 93-97. 2 2011. (PDF)
  1. Oxovanadium(IV) cyclam and bicyclam complexes: potential CXCR4 receptor antagonists. Ross, A.; Soares, D., C.; Covelli, D.; Pannecouque, C.; Budd, L.; Collins, A.; Robertson, N.; Parsons, S.; De Clercq, E.; Kennepohl, P.; and Sadler, P., J. Inorg. Chem., 49(3): 1122-32. 2 2010. (PDF)
  2. Blueprint XAS: a Matlab-based toolbox for the fitting and analysis of XAS spectra. Delgado-Jaime, M., U.; Mewis, C., P.; and Kennepohl, P. J. Synchrotron Rad., 17(1): 132-7. 1 2010. (PDF)
  3. Development and exploration of a new methodology for the fitting and analysis of XAS data. Delgado-Jaime, M., U.; and Kennepohl, P. J. Synchrotron Rad., 17(1): 119-28. 1 2010. (PDF)
  4. X-ray spectroscopic approaches to the investigation and characterization of photochemical processes. Erratum. Kennepohl, P.; Wasinger, E., C.; and DeBeer George, S. Journal of Synchrotron Radiation, 17(1): 138-138. 1 2010. (PDF)
  5. Oxovanadium(IV) cyclam and bicyclam complexes: Potential CXCR4 receptor antagonists. Ross, A.; Soares, D., C.; Covelli, D.; Pannecouque, C.; Budd, L.; Collins, A.; Robertson, N.; Parsons, S.; De Clercq, E.; Kennepohl, P.; and Sadler, P., J. Inorg. Chem., 49(3): 112.  (PDF)

2009

  1. Abnormal Reactivity of an N-Heterocyclic Carbene (NHC) with a Phosphaalkene: A Route to a 4-Phosphino-Substituted NHC. Bates, J., I.; Kennepohl, P.; and Gates, D., P. Angew. Chem. Int. Ed., 48(52): 9844-9847. 12 2009. (PDF)
  2. Effects of Hyperconjugation on the Electronic Structure and Photoreactivity of Organic Sulfonyl Chlorides. Martin-Diaconescu, V.; and Kennepohl, P. Inorg. Chem., 48(3): 1038-1044. 2 2009. (PDF)
  3. Influence of oxygenation on the reactivity of ruthenium-thiolato bonds in arene anticancer complexes: insights from XAS and DFT. Sriskandakumar, T.; Petzold, H.; Bruijnincx, P., C., A.; Habtemariam, A.; Sadler, P., J.; and Kennepohl, P. J. Am. Chem. Soc., 131(37): 13355-61. 9 2009. (PDF)
  4. Redox photochemistry of methionine by sulfur K-edge X-ray absorption spectroscopy: potential implications for cataract formation. Karunakaran-Datt, A.; and Kennepohl, P. J. Am. Chem. Soc., 131(10): 3577-82. 3 2009. (PDF)
  5. X-ray spectroscopic approaches to the investigation and characterization of photochemical processes. Kennepohl, P.; Wasinger, E., C.; and DeBeer George, S. J. Synchrotron Rad., 16(4): 484-488. 7 2009. (PDF)

2008

  1. Assignment of pre-edge features in the Ru K-edge X-ray absorption spectra of organometallic ruthenium complexes. Getty, K.; Delgado-Jaime, M., U.; and Kennepohl, P. Inorg. Chim. Acta, 361(4): 1059-1065. 3 2008.  (PDF)
     
  2. N-heterocyclic carbene complexes of Rh: reaction with dioxygen without oxidation. Praetorius, J., M.; Allen, D., P.; Wang, R.; Webb, J., D.; Grein, F.; Kennepohl, P.; and Crudden, C., M. J. Am. Chem. Soc., 130(12): 3724-5. 3 2008. (PDF)

2007

  1. Probing electronic communication in stable benzene-bridged verdazyl diradicals. Gilroy, J., B.; McKinnon, S., D., J.; Kennepohl, P.; Zsombor, M., S.; Ferguson, M., J.; Thompson, L., K.; and Hicks, R., G. J. Org. Chem., 72(21): 8062-8069. 10 2007. (PDF)
  2. An electronic rationale for observed initiation rates in ruthenium-mediated olefin metathesis: charge donation in phosphine and N-heterocyclic carbene ligands. Getty, K.; Delgado-Jaime, M., U.; and Kennepohl, P. J. Am. Chem. Soc., 129(51): 15774-6. 12 2007. (PDF)
  3. Sulfur K-edge XAS as a probe of sulfur-centered radical intermediates. Martin-Diaconescu, V.; and Kennepohl, P. J. Am. Chem. Soc., 129(11): 3034-5. 3 2007. (PDF)

2006

  1. X-ray absorption methods for the determination of Ru–Cl bond covalency in olefin metathesis catalysts: On the normalization of chlorine K-edges in ruthenium complexes. Delgado-Jaime, M., U.; Conrad, J., C.; Fogg, D., E.; and Kennepohl, P. Inorg. Chim. Acta, 359(9): 3042-3047. 6 2006. (PDF)

 2005

  1. Variable energy photoelectron spectroscopy: electronic structure and electronic relaxation. Solomon, E., I.; Basumallick, L.; Chen, P.; and Kennepohl, P. Coord. Chem. Rev., 249(1-2): 229-253. 1 2005. (PDF)
  2. Spectroscopy of non-heme iron thiolate complexes: insight into the electronic structure of the low-spin active site of nitrile hydratase. Kennepohl, P.; Neese, F.; Schweitzer, D.; Jackson, H., L.; Kovacs, J., A.; and Solomon, E., I. Inorg. Chem., 44(6): 1826-36. 3 2005. (PDF)

  2004

  1. X-ray magnetic circular dichroism of Pseudomonas aeruginosa nickel(II) azurin.  Funk, T.; Kennepohl, P.; Di Bilio, A., J.; Wehbi, W., a.; Young, A., T.; Friedrich, S.; Arenholz, E.; Gray, H., B.; and Cramer, S., P. J. Am. Chem. Soc., 126(18): 5859-66. 5 2004. (PDF)
  2. Spectroscopy and Electronic Structure of [FeX4]n-(X=Cl, SR). Kennepohl, P.; and Solomon, E., I. Volume 2 2004. (PDF)

2003

  1. Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 1. Photoelectron spectroscopic determination of electronic relaxation. Kennepohl, P.; and Solomon, E., I. Inorg. Chem., 42(3): 679-88. 2 2003. (PDF)
  2. Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 2. Reduction potentials. Kennepohl, P.; and Solomon, E., I. Inorg. Chem., 42(3): 689-95. 2 2003. (PDF)
  3. Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 3. Kinetics of electron transfer. Kennepohl, P.; and Solomon, E., I. Inorg. Chem., 42(3): 696-708. 2 2003. (PDF)

1997

  1. A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes. Westre, T., E.; Kennepohl, P.; DeWitt, J., G.; Hedman, B.; Hodgson, K., O.; and Solomon, E., I. J. Am. Chem. Soc., 119(27): 6297-6314. 7 1997. (PDF)

1996

  1. Structural and Functional Aspects of Metal Sites in Biology. Holm, R., H.; Kennepohl, P.; and Solomon, E., I. Chem. Rev., 96(7): 2239-2314. 1 1996. (PDF)

 1994

  1. Reduction and Aggregation of Silver Ions at the Surface of Colloidal Silica. Lawless, D.; Kapoor, S.; Kennepohl, P.; Meisel, D.; and Serpone, N. J. Phys. Chem., 98(38): 9619-9625. 9 1994.(PDF)
  2. Reduction and Aggregation of Silver in Aqueous Gelatin and Silica Suspensions. Kapoor, S.; Lawless, D.; Kennepohl, P.; and Meisel, D. In ICPS `94: The Physics and Chemistry os Imaging Systems, pages 57-60, 1994. (PDF)
  3. Reduction and Aggregation of Silver Ions in Aqueous Gelatin Solutions. Kapoor, S.; Lawless, D.; Kennepohl, P.; Meisel, D.; and Serpone, N. Langmuir, 10(9): 3018-3022. 9 1994. (PDF)

 1993

  1. On the usage of turnover numbers and quantum yields in heterogeneous photocatalysis. Serpone, N.; Terzian, R.; Lawless, D.; Kennepohl, P.; and Sauvé, G. J. Photochem. Photobiol. A, 73(1): 11-16. 6 1993. (PDF)
  2. Thin films of non-stoichiometric perovskites as potential oxygen sensors. Post, M., L.; Sanders, B., W.; and Kennepohl, P. Sensors and Actuators B: Chemical, 13(1-3): 272-275. 5 1993. (PDF)